It was first seen by the German expedition of 1873-74, but not traversed until December 1898, when the Belgica of the Belgian Antarctic Expedition passed through. Expedition leader Adrien de Gerlache named it for Charles Lemaire, a Belgian explorer of the Congo.
The channel has since become a standard part of the itinerary for cruising in Antarctica; not only is it scenic, but the protected waters are usually as still as a lake, a rare occurrence in the storm-wracked southern seas, and the north-south traverse delivers vessels close to Petermann Island for landings. The principal difficulty is that icebergs may fill the channel, especially in early season, obliging a ship to backtrack and go around the outside of Booth Island to reach Petermann.
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