Most of the canyon is protected; it is governed by the Réserve Naturelle Gorges de l'Ardèche. Notable sights along the canyon include the Pont d'Arc at the beginning of the canyon, a natural arch 60 m wide and 54 m high. Much of the canyon is inaccessible except by water, and canoeing and kayaking are popular sports on the river. Overnight camping is not allowed, except for at two bivouac shelters.
The cliffs offer habitat to rare birds such as the Bonelli's eagle.
Humans have lived in caves in the area for over 300,000 years. Over 2,000 caves are found in the gorge, some of them painted; the best-known painted cave in the gorge is the Chauvet Cave.
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